Intermolecular Hydrogen Bonding of ReH2(CO)(NO)L2 Hydrides with Perfluoro-tert-butyl Alcohol. Competition between M−H···H−OR and M−NO···H−OR Interactions

Autor:	Heiko Jacobsen, Heinz Berke, and Andreas Messmer, Aleksei V. Ionidis, Natalia V. Belkova, L.M. Epstein, Elena S. Shubina
Rok vydání:	1997
Předmět:	Steric effects Hydrogen bond Intermolecular force Infrared spectroscopy Alcohol Photochemistry Perfluoro-tert-butyl alcohol Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Physical and Theoretical Chemistry Phosphine
Zdroj:	Inorganic Chemistry. 36:1522-1525
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic9608298
Popis:	The interactions of the title compounds ReH2(CO)(NO)L2 (L = PMe3, PEt3, PiPr3) with perfluoro-tert-butyl alcohol (PFTB) have been studied by IR spectroscopy. The steric requirements of the phosphine ligands take a strong influence on the hydrogen-bonding site at the metal center and determine whether RO−H···H−M and/or RO−H···ON−M bonding modes are realized. The experimental findings are supported by density functional calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a40a1a9fb3907c4ca14189c7be45b46f https://doi.org/10.1021/ic9608298 Zobrazit plný text záznamu