An Ancient Egyptian Multilayered Polychrome Wooden Sculpture Belonging to the Museo Egizio of Torino: Characterization of Painting Materials and Design of Cleaning Processes by Means of Highly Retentive Hydrogels

Autor: Paola Buscaglia, M. Nervo, Alessandro Borghi, Alessandro Re, Dominique Maria Scalarone, Laura Guidorzi, Paolo Gallo, Alessandro Lo Giudice, Sara Aicardi, Piero Baglioni, Nicole Manfredda, Giovanna Poggi, Matilde Borla
Jazyk: angličtina
Předmět:
Materials science
Infrared
020209 energy
Ancient Egyptian
Ancient Egyptian painting materials
Archaeometry
Cleaning treatment
Conservation
Cultural heritage
Poly(vinyl alcohol) hydrogels
Water based systems
Wooden sculpture
Multispectral image
poly(vinyl alcohol) hydrogels
02 engineering and technology
water based systems
01 natural sciences
Archaeological science
Egyptian blue
chemistry.chemical_compound
cleaning treatment
0202 electrical engineering
electronic engineering
information engineering

Materials Chemistry
Polychrome
Painting
Spectrometer
010401 analytical chemistry
Metallurgy
conservation
Surfaces and Interfaces
cultural heritage
Engineering (General). Civil engineering (General)
ancient Egyptian painting materials
0104 chemical sciences
Surfaces
Coatings and Films

Characterization (materials science)
ancient Egyptian
cultural heritage
conservation
wooden sculpture
ancient Egyptian
ancient Egyptian painting materials
cleaning treatment
water based systems
poly(vinyl alcohol) hydrogels
archaeometry

wooden sculpture
archaeometry
chemistry
TA1-2040
Zdroj: Coatings
Volume 11
Issue 11
Coatings, Vol 11, Iss 1335, p 1335 (2021)
ISSN: 2079-6412
DOI: 10.3390/coatings11111335
Popis: This contribution focuses on the conservation of an Egyptian wooden sculpture (Inventory Number Cat. 745) belonging to the Museo Egizio of Torino in northwest Italy. A preliminary and interdisciplinary study of constituent painting materials and their layering is here provided. It was conducted by means of a multi-technique approach starting from non-invasive multispectral analysis on the whole object, and subsequently, on selected micro-samples. In particular, visible fluorescence induced by ultraviolet radiation (UVF), infrared reflectography (IRR) and visible--induced infrared luminescence were used on the whole object. The micro-samples were analysed by means of an optical microscope with visible and UV light sources, a scanning electron microscope (SEM) with an energy-dispersive X-ray spectrometer (EDX), Fourier transform infrared (FT-IR) spectrometer, pyrolysis-gas chromatography/mass spectrometer (Py-GC/MS) and micro-particle induced X-ray emission (PIXE). The characterization of the painting materials allowed the detection of Egyptian blue and Egyptian green, and also confirmed the pertinence of the top brown layer to the original materials, which is a key point to design a suitable surface treatment. In fact, due to the water sensitiveness of the original materials, only few options were available to perform cleaning operations on this artwork. To setup the cleaning procedure, we performed several preliminary tests on mockups using dry cleaning materials, commonly used to treat reactive surfaces, and innovative highly water retentive hydrogels, which can potentially limit the mechanical action on the original surface while proving excellent cleaning results. Overall, this study has proved fundamental to increase our knowledge on ancient Egyptian artistic techniques and contribute to hypothesize the possible provenance of the artefact. It also demonstrated that polyvinyl alcohol-based retentive gels allow for the safe and efficient cleaning of extremely water sensitive painted surfaces, as those typical of ancient Egyptian artefacts.
Databáze: OpenAIRE