Two organic–inorganic hybrid compounds constructed from [PMoV1MoVI7VIV2VV4O42]4− and different transition metal fragments

Autor:	Shu-Yun Shi, Xiao-Bing Cui, Tong-Hui Zhu
Rok vydání:	2017
Předmět:	010405 organic chemistry Chemistry Hydrogen bond Supramolecular chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Transition metal TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY Organic inorganic Polyoxometalate Materials Chemistry Organic chemistry Hydrothermal synthesis Physical and Theoretical Chemistry
Zdroj:	Journal of Coordination Chemistry. 70:790-802
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2017.1278755
Popis:	Two new organic–inorganic hybrid compounds, [Cu(phen)(prz)]2[PMoV1MoVI7VIV2VV4O42]·4H2O (1) and [Ag2(phen)4]2[PMoV1MoVI7VIV2VV4O42] (2) (phen = 1,10-phenanthroline, prz = pyrazine), have been synthesized and characterized by IR, XPS, XRD, UV–vis, fluorescent spectra analyses, elemental analyses, X-ray diffraction analyses, TG analyses, and cyclic voltammetric measurements. Both compounds are formed by Keggin POM cores and transition metal fragments. Compound 1 exhibits an unprecedented 1-D chain structure constructed from [PMoV1MoVI7VIV2VV4O42]4− and [Cu(phen)(prz)]2+ in the –A–B↑–C–B↓– linking mode. Compound 2 shows a supramolecular structure formed by [PMoV1MoVI7VIV2VV4O42]4− and [Ag2(phen)4]2+.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a38650311cd18ef5ea3f34f77639a54b https://doi.org/10.1080/00958972.2017.1278755 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.