Polyborosilazanes with Controllable B/N Ratio for Si–B–C–N Ceramics

Autor: Yanpei Dang, Tianhao Li, Yangzhong Zhao, Liantai Duan, Jianning Zhang, Ke Chen, Liu He, Qing Huang, Chuanzhuang Zhao, Yujie Song
Rok vydání: 2023
Předmět:
Zdroj: Materials
Volume 16
Issue 3
Pages: 1053
ISSN: 1996-1944
DOI: 10.3390/ma16031053
Popis: Polyborosilazanes with controllable B/N ratio were synthesized using high-boron-content m-carborane, dichloromethylsilane, and hexamethydisilazane. After high-temperature pyrolysis, Si–B–C–N quaternary ceramics with SiC and B4C as the main phases were obtained. The B/N ratio in the precursors corresponded to the change in the feeding ratio of carborane and dichloromethylsilane. The effects of boron content and B/N ratio on the ceramic precursors and microphase structure in Si–B–C–N quaternary ceramics were explored in detail through a series of analytical characterization methods. A high boron content results in a significant increase in the ceramic yield (up to 71 wt%) of polyborosilazanes, and at the same time, the B/N molar ratio was regulated from 28.4:1 to 1.62:1. The appearance of the B4C structure in the Si–B–C–N quaternary ceramics through the regulation of the B/N ratio, has rarely been reported.
Databáze: OpenAIRE
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