Synthesis and Characterization of Photothermal Osmium Carbolong Complexes
| Autor: | Chun Tang, Zhixin Chen, Zhengyu Lu, Haiping Xia, Jianfeng Lin, Qin Lin, Shenyan Li, Jiangxi Chen, Xumin He, Meijin Chen |
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| Rok vydání: | 2018 |
| Předmět: |
Reaction mechanism
Denticity 010405 organic chemistry Organic Chemistry chemistry.chemical_element General Chemistry Photothermal therapy 010402 general chemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Characterization (materials science) chemistry Anhydrous Chelation Osmium Carbon |
| Zdroj: | Chemistry - A European Journal. 24:8375-8381 |
| ISSN: | 0947-6539 |
| DOI: | 10.1002/chem.201800656 |
| Popis: | Metallacycles with chelating polydentate conjugated-carbon chain ligands are called carbolong complexes, which are expected to have interesting properties. In this work, the preparation of 12-carbon carbolong complexes in which all of the coordinated atoms in the equatorial plane are carbon atoms was studied. With the help of the well-established mechanism, a new approach to prepare coplanar carbolong complexes bearing different organic functional groups was developed by adding different terminal alkynes in sequence. In the presence of HBF4 , these coplanar carbolong complexes were converted to η3 -allyl osmapentalene derivatives, which can be produced directly from the reaction of cyclopropaosmapentalene 1 with terminal alkynes in the presence of AgBF4 under anhydrous conditions. This study offers a new route for the preparation of functional osmium carbolong complexes with excellent photothermal properties, which can be used to prepare photothermal materials. |
| Databáze: | OpenAIRE |
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