Amphiphilic Allylic Alkylation with Allyl Alcohols Promoted by Pd-Catalyst and Triethylborane

Autor:	Masanari Kimura, Yoshinao Tamaru
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Allylic rearrangement Aldimine Allyl alcohol Triethylborane Organic Chemistry Medicinal chemistry Pyrrolidine chemistry.chemical_compound Tsuji–Trost reaction chemistry Nucleophile Electrophile Amphiphilic allylation Palladium
Zdroj:	Mini-Reviews in Organic Chemistry. 6:392-397
ISSN:	1570-193X
DOI:	10.2174/157019309789371631
Popis:	The combination of Pd catalyst and triethylborane induces allylic alcohols to undergo direct electrophilic allylation of soft nucleophiles. Similar conditions also accelerate nucleophilic allylations of aldehydes and aldimines to provide homoallyl alcohols and homoallylamines, respectively. Moreover, 2-methylenepropane-1,3-diol undergoes a sequential amphiphilic activation to react with aldehydes and aldimines, giving rise to 3-methylenecyclopentanols and 3-methylenepyrrolidines. Mini-Reviews in Organic Chemistry, 6(4), pp.392-397, 2009
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a339f2e7613f539cfcfec69263d89201 https://doi.org/10.2174/157019309789371631 Zobrazit plný text záznamu