Cobalt(III)-Catalyzed Chemo- and Regioselective [4 + 2]-Annulation of Aromatic Sulfoxonium Ylides with 1,3-Diynes

Autor:	Suresh Kumar Yadav, Balu Ramesh, Masilamani Jeganmohan
Rok vydání:	2022
Předmět:	Diynes Alkynes Organic Chemistry Cobalt Naphthols Catalysis
Zdroj:	The Journal of Organic Chemistry. 87:4134-4153
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.1c02967
Popis:	Air-stable, highly abundant, and cost-effective Co(III)-catalyzed redox-neutral [4 + 2]-annulation of aromatic sulfoxonium ylides with 1,3-diynes providing useful substituted 1-naphthol derivatives in a regioselective manner is described. Further, the prepared 1-naphthols having internal alkyne were converted into useful polycarbocyclic molecules and spiro-dienone derivatives in good-to-excellent yields. A possible reaction mechanism involving
Databáze:	OpenAIRE
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