| Autor: |
Hong Lin, Meixian Li, Lu Liu, Shukuan Wang, Xiaopei Miao, Jingbo Hu, Baoyun Sun |
| Jazyk: |
angličtina |
| Rok vydání: |
2010 |
| Předmět: |
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| Zdroj: |
Electrochemistry Communications, Vol 12, Iss 1, Pp 90-93 (2010) |
| ISSN: |
1388-2481 |
| Popis: |
A new ferrocenecarboxylic acid–C60 composite (Fc–C60) has been synthesized by controlled potential electrolysis. A composite modified glassy carbon electrode has been prepared based on its good electrochemical activity. The modified electrode in 0.1 M NaClO4 solution shows a reversible oxidation wave at E1/2 = 0.32 V (vs. SCE) attributed to the oxidation of the ferrocene entity and a quasi-reversible reduction wave of C60 entity at E1/2 = −0.54 V (vs. SCE). Electrocatalytic studies show that Fc–C60 at the modified electrode can mediate the reduction of hydrogen peroxide (H2O2), and a broad linear range from 1.2 μM to 21.9 mM for H2O2 were obtained with a determination limit of 2.5 × 10−7 M by amperometry. Keywords: C60, Electrochemistry, Ferrocenecarboxylic acid, Electrocatalysis, Hydrogen peroxide |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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