Paddlewheelite, a New Uranyl Carbonate from the Jáchymov District, Bohemia, Czech Republic

Autor: Travis A. Olds, Jakub Plášil, Anthony R. Kampf, Fabrice Dal Bo, Peter C. Burns
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Minerals
Volume 8
Issue 11
Minerals, Vol 8, Iss 11, p 511 (2018)
ISSN: 2075-163X
DOI: 10.3390/min8110511
Popis: Paddlewheelite, MgCa5Cu2[(UO2)(CO3)3]4·
33H2O, is a new uranyl carbonate mineral found underground in the Svornost mine, Já
chymov District, Bohemia, Czech Republic, where it occurs as a secondary oxidation product of uraninite. The conditions leading to its crystallization are complex, likely requiring concomitant dissolution of uraninite, calcite, dolomite, chalcopyrite, and andersonite. Paddlewheelite is named after its distinctive structure, which consists of paddle-wheel clusters of uranyl tricarbonate units bound by square pyramidal copper &ldquo
axles&rdquo
and a cubic calcium cation &ldquo
gearbox.&rdquo
Paddle wheels share edges with calcium polyhedra to form open sheets that are held together solely by hydrogen bonding interactions. The new mineral is monoclinic, Pc, a = 22.052(4), b = 17.118(3), c = 19.354(3) Å
&beta
= 90.474(2)°
V = 7306(2) Å
3 and Z = 4. Paddlewheelite is the second-most structurally complex uranyl carbonate mineral known after ewingite and its structure may provide insights into the insufficiently described mineral voglite, as well as Cu&ndash
U&ndash
CO3 equilibrium in general.
Databáze: OpenAIRE
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