Detection of vibrationally excited HC7N and HC9N in IRC +10216
| Autor: | L. Velilla-Prieto, Carlos Cabezas, Celina Bermúdez, M. Guelin, G. Quintana-Lacaci, Belén Tercero, Marcelino Agúndez, J. D. Gallego, José Cernicharo, José Pablo Fonfría, Juan R. Pardo |
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| Přispěvatelé: | Ministerio de Economía y Competitividad (España), European Research Council, European Commission, Swedish Research Council |
| Rok vydání: | 2020 |
| Předmět: |
Astrochemistry
010504 meteorology & atmospheric sciences Infrared Line: identification Astrophysics 01 natural sciences 7. Clean energy Article Ab initio quantum chemistry methods 0103 physical sciences identification [Line] Spectroscopy 010303 astronomy & astrophysics Stars: individual: IRC+10216 0105 earth and related environmental sciences Physics Molecular data individual: IRC+10216 [Stars] Astronomy and Astrophysics Circumstellar matter Quantum number 3. Good health Stars: carbon Space and Planetary Science Excited state Rotational spectroscopy Atomic physics Ground state carbon [Stars] |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname Astron Astrophys |
| Popis: | 12 pags., 8 figs., 8 tabs.-- Section: Letters to the Editor Observations of IRC +10216 with the Yebes 40 m telescope between 31 and 50 GHz have revealed more than 150 unidentified lines. Some of them can be grouped into a new series of 26 doublets, harmonically related with integer quantum numbers ranging from Jup = 54 to 80. The separation of the doublets increases systematically with J, that is to say, as expected for a linear species in one of its bending modes. The rotational parameters resulting from the fit to these data are B = 290.8844 ± 0.0004 MHz, D = 0.88 ± 0.04 Hz, and q = 0.1463 ± 0.0001 MHz. The rotational constant is very close to that of the ground state of HC9N. Our ab initio calculations show an excellent agreement between these parameters and those predicted for the lowest energy vibrationally excited state, ν19 = 1, of HC9N. This is the first detection, and complete characterization in space, of vibrationally excited HC9N. An energy of 41.5 cm-1 is estimated for the ν19 state. In addition, 17 doublets of HC7N in the ν15 = 1 state, for which laboratory spectroscopy is available, were detected for the first time in IRC +10216. Several doublets of HC5N in its ν11 = 1 state were also observed. The column density ratio between the ground and the lowest excited vibrational states are ≈127, 9.5, and 1.5 for HC5N, HC7N, and HC9N, respectively. We find that these lowest-lying vibrational states are most probably populated via infrared pumping to vibrationally excited states lying at ≈600 cm-1. The lowest vibrationally excited states thus need to be taken into account to precisely determine absolute abundances and abundance ratios for long carbon chains. The abundance ratios N(HC5N)/N(HC7N) and N(HC7N)/N(HC9N) are 2.4 and 7.7, respectively. he Spanish authors thank Ministerio de Ciencia e Innovación for funding support through project AYA2016-75066-C2-1-P. We also thank ERC for funding through grant ERC-2013-Syg-610256-NANOCOSMOS. MA thanks Ministerio de Ciencia e Innovación for Ramón y Cajal grant RyC2014-16277. CB thanks Ministerio de Ciencia e Innovación for Juan de la Cierva grant FJCI-2016-27983. LVP acknowledges support from the Swedish Research Council and from the ERC through the consolidator |
| Databáze: | OpenAIRE |
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