H2O2 Generation by Decamethylferrocene at a Liquid|Liquid Interface

Autor:	Fei Li, Hubert H. Girault, Michel Prudent, Zdenek Samec, Mohamad Hojeij, Bin Su, Raheleh Partovi Nia, Clémence Corminboeuf
Rok vydání:	2008
Předmět:	Reducing agent Inorganic chemistry Aqueous two-phase system Analytical chemistry chemistry.chemical_element General Medicine General Chemistry Electron Oxygen Catalysis Decamethylferrocene chemistry.chemical_compound chemistry Yield (chemistry) Liquid liquid Hydrogen peroxide
Zdroj:	Angewandte Chemie International Edition. 47:4675-4678
ISSN:	1521-3773 1433-7851
DOI:	10.1002/anie.200801004
Popis:	Hydrogen peroxide generation at a liquid|liquid interface occurs with a yield of 20 % with respect to the concentration of reducing agent (decamethylferrocene). The liquid|liquid interface supplies electrons from the reducing agent and protons from the aqueous phase to drive the reduction of O2 into H2O2, which is extracted into the aqueous phase during the course of reaction (see picture; DCE=1,2-dichloroethane).
Databáze:	OpenAIRE
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