The synthesis of regio-regular poly(3-alkyl-2,5-thienylene vinylene) derivatives using lithium bis(trimethylsilyl)amide (LHMDS) in the dithiocarbamate precursor route
| Autor: | Fateme Banishoeib, Jean Manca, Olivier Douheret, Thomas J. Cleij, Peter Adriaensens, Sofie Fourier, Laurence Lutsen, D. Vanderzande, Stéphane Guillerez, Solenn Berson |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
chemistry.chemical_classification
conjugated polymer Trimethylsilyl Renewable Energy Sustainability and the Environment Lithium bis(trimethylsilyl)amide chemistry.chemical_element Conjugated system PTV Chemical synthesis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry precursor polymer low band gap Amide Polymer chemistry Lithium Dithiocarbamate Alkyl |
| Zdroj: | Solar Energy Materials and Solar Cells, 91(11), 1026-1034. Elsevier |
| ISSN: | 0927-0248 |
| DOI: | 10.1016/j.solmat.2007.02.013 |
| Popis: | Poly(2,5-thienylene vinylene) derivatives (ptvs) present a specific class of low band gap conjugated polymers of which the synthesis seems to be problematic. Recently, the dithiocarbamate route was introduced as a synthetic route towards ptv. However, the synthesis of alkyl-ptv derivatives failed on using lithium diisopropyl amide (lda) as the base in the polymerisation reaction. We demonstrate that the use of lithium bis(trimethylsilyl)amide (lhmds) instead of lda allows for an efficient synthesis of alkyl-ptv derivatives. Indications are presented for the formation of an ordered structure in case of the 3-alkyl derivative, pointing to a regio-regular polymerisation process. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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