On the study of catalytic membrane reactor for water detritiation: Modeling approach
| Autor: | Xavier Joulia, Karine Liger, Michèle Troulay, Jérémy Mascarade, Christophe Perrais, Xuan-Mi Meyer |
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| Přispěvatelé: | Service Mesures et modélisation des Transferts et des Accidents graves (SMTA), Département Technologie Nucléaire (DTN), CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-CEA-Direction des Energies (ex-Direction de l'Energie Nucléaire) (CEA-DES (ex-DEN)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Laboratoire de génie chimique [ancien site de Basso-Cambo] (LGC), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées, Commissariat à l'Energie Atomique et aux énergies alternatives - CEA (FRANCE), Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Laboratoire de Génie Chimique - LGC (Toulouse, France), Laboratoire de Génie Chimique (LGC), Université de Toulouse (UT)-Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT), Institut National Polytechnique de Toulouse - INPT (FRANCE) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Materials science
Tritiated water Thermodynamic equilibrium Thermodynamics 01 natural sciences 7. Clean energy Catalytic membrane reactor 010305 fluids & plasmas Catalysis Chemical kinetics chemistry.chemical_compound [CHIM.GENI]Chemical Sciences/Chemical engineering 0103 physical sciences Génie chimique General Materials Science Detritiation 010306 general physics Civil and Structural Engineering Packed bed Membrane reactor Mechanical Engineering 6. Clean water Membrane Nuclear Energy and Engineering Deuterium chemistry |
| Zdroj: | Fusion Engineering and Design Fusion Engineering and Design, Elsevier, 2016, 109-111, pp.1412-1416. ⟨10.1016/j.fusengdes.2015.12.009⟩ Fusion Engineering and Design, 2016, 109-111, pp.1412-1416. ⟨10.1016/j.fusengdes.2015.12.009⟩ |
| ISSN: | 0920-3796 |
| Popis: | International audience; In the framework of tritium recovery from tritiated water, efficiency of packed bed membrane reactors have been successfully demonstrated. Thanks to protium isotope swamping, tritium bonded water can be recovered under the valuable Q2 form (Q = H, D or T) by means of isotope exchange reactions occurring on catalyst surface. The use of permselective Pd-based membrane allows withdrawal of reactions products all along the reactor, and thus limits reverse reaction rate to the benefit of the direct one (shift effect). The reactions kinetics, which are still little known or unknown, are generally assumed to be largely greater than the permeation ones so that thermodynamic equilibriums of isotope exchange reactions are generally assumed. This paper proposes a new phenomenological 2D model to represent catalytic membrane reactor behavior with the determination of gas effluents compositions. A good agreement was obtained between the simulation results and experimental measurements performed on a dedicated facility. Furthermore, the gas composition estimation permits to interpret unexpected behavior of the catalytic membrane reactor. In the next future, further sensitivity analysis will be performed to determine the limits of the model and a kinetics study will be conducted to assess the thermodynamic equilibrium of reactions |
| Databáze: | OpenAIRE |
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