Copper(I) Complexes of Fluorinated Triazapentadienyl Ligands: Synthesis and Characterization of [N{(C3F7)C(Dipp)N}2]CuL (Where L = NCCH3, CNBut, CO; Dipp = 2,6-Diisopropylphenyl)

Autor:	H. V. Rasika Dias, Shreeyukta Singh
Rok vydání:	2004
Předmět:	Steric effects Stereochemistry Ligand Isocyanide Oxide chemistry.chemical_element Copper Medicinal chemistry Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Physical and Theoretical Chemistry Acetonitrile
Zdroj:	Inorganic Chemistry. 43:5786-5788
ISSN:	1520-510X 0020-1669
Popis:	Sterically demanding triazapentadiene [N[(C3F7)C(Dipp)N]2] H has been synthesized in good yield. It features a W-shaped ligand backbone in the solid state. [N[(C3F7)C(Dipp)N]2]H reacts with copper(I) oxide in acetonitrile leading to [N[(C3F7)C(Dipp)N]2]CuNCCH3. This copper adduct serves as an excellent precursor to obtain thermally stable [N[(C3F7)C(Dipp)N]2]CuCNBut and [N[(C3F7)C(Dipp)N]2]CuCO. IR spectroscopic data of these copper(I) isocyanide (CN = 2176 cm(-1)) and copper(I) carbonyl (CO = 2109 cm(-1)) complexes indicate that the [N[(C3F7)C(Dipp)N]2]- ligand is a fairly weak donor.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a1bc39ae5055ba866ce15cd4f6ddd765 https://doi.org/10.1021/ic049229w Zobrazit plný text záznamu