Cyclic Alumosiloxanes and Alumosilicates: Exemplifying the Loewenstein Rule at the Molecular Level
Autor: | Mónica Moya-Cabrera, Vojtech Jancik, Sandra González-Gallardo, Alma A. Delgado-Robles |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Inorganic Chemistry. 50:4226-4228 |
ISSN: | 1520-510X 0020-1669 |
DOI: | 10.1021/ic200313k |
Popis: | The cyclic alumosiloxane [{LAl(μ-O)(Ph(2)Si)(μ-O)}(2)] (3) and alumosilicate [{LAl(μ-O){((t)BuO)(2)Si}(μ-O)}(2)] (4) were obtained by reaction of the appropriate R(2)Si(OH)(2) precursor (R = Ph, O(t)Bu) with [{LAl(H)}(2)(μ-O)] (1), providing a nice illustration of the Loewenstein rule at work at the molecular level. |
Databáze: | OpenAIRE |
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