Two homochiral organocatalytic metal organic materials with nanoscopic channels
| Autor: | Zhuxiu Zhang, Lukasz Wojtas, Michael J. Zaworotko, Shengqian Ma, Young Ran Ji, Jon C. Antilla, Wen-Yang Gao |
|---|---|
| Rok vydání: | 2013 |
| Předmět: |
biology
Chemistry Ligand Metals and Alloys Context (language use) General Chemistry Transfer hydrogenation biology.organism_classification Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound visual_art Polymer chemistry Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Tetra Organic chemistry Nanoscopic scale Phosphoric acid |
| Zdroj: | Chemical Communications. 49:7693 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c3cc43801e |
| Popis: | Two homochiral organocatalytic MOMs were prepared using tetra- and octa-carboxylate ligands, respectively. The nanoscopic channels in these MOMs are lined by organonocatalytic chiral phosphoric acid derivatives of binol and ocMOM-1 exhibited improved enantioselectivity over the parent ligand in the context of transfer hydrogenation of a series of benzoxazines. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|