Combinatorial Synthesis and High-Throughput Characterization of Fe-V-O Thin-Film Materials Libraries for Solar Water Splitting
Autor: | Swati Kumari, Wolfgang Schuhmann, Katharina Hengge, Christina Scheu, Ramona Gutkowski, Alfred Ludwig, Aleksander Kostka, João R. C. Junqueira |
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Rok vydání: | 2018 |
Předmět: |
Annealing (metallurgy)
Iron 02 engineering and technology 010402 general chemistry 01 natural sciences Catalysis Solar water Electron Transport Small Molecule Libraries Crystallinity Third phase Solar Energy Combinatorial Chemistry Techniques Thin film Photocurrent Chemistry Water Oxides Vanadium General Chemistry General Medicine Electrochemical Techniques 021001 nanoscience & nanotechnology Microstructure Photochemical Processes 0104 chemical sciences Oxygen Chemical engineering Transmission electron microscopy 0210 nano-technology Hydrogen |
Zdroj: | ACS combinatorial science. 20(9) |
ISSN: | 2156-8944 |
Popis: | The search for suitable materials for solar water splitting is addressed with combinatorial material science methods. Thin film Fe–V–O materials libraries were synthesized using combinatorial reactive magnetron cosputtering and subsequent annealing in air. The design of the libraries comprises a combination of large compositional gradients (from Fe10V90Ox to Fe79V21Ox) and thickness gradients (from 140 to 425 nm). These material libraries were investigated by high-throughput characterization techniques in terms of composition, structure, optical, and photoelectrochemical properties to establish correlations between composition, thickness, crystallinity, microstructure, and photocurrent density. Results show the presence of the Fe2V4O13 phase from ∼11 to 42 at. % Fe (toward low-Fe region) and the FeVO4 phase from ∼37 to 79 at. % Fe (toward Fe-rich region). However, as a third phase, Fe2O3 is present throughout the compositional gradients (from low-Fe to Fe-rich region). Material compositions with increasin... |
Databáze: | OpenAIRE |
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