On the Correlation between Pair Hydrophobicity and Mixing Enthalpies in Water-Alcohol Binary Mixtures
| Autor: | Ritaban Halder, Biman Jana |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010304 chemical physics
Chemistry Binary number Thermodynamics Alcohol macromolecular substances 010402 general chemistry 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Chain length chemistry.chemical_compound 0103 physical sciences Materials Chemistry Physical and Theoretical Chemistry Mixing (physics) |
| Zdroj: | The journal of physical chemistry. B. 124(37) |
| ISSN: | 1520-5207 |
| Popis: | In this article, we have explored the extent of pair hydrophobicity in water-alcohol binary mixtures upon varying the chain length of the alcohol at several compositions. We have measured the pair hydrophobicity in water-methanol, water-propanol, and water-butanol mixtures. The pair hydrophobicity is measured by the depth of the first minimum (contact minimum) in the potential of mean force profile between a pair of neopentanes. In the case of water-methanol mixtures, the pair hydrophobicity is highest at |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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