Lyotropic Liquid-Crystalline Solutions of High-Concentration Dispersions of Single-Walled Carbon Nanotubes with Conjugated Polymers
| Autor: | Melburne C. Lemieux, Soumendra N. Barman, Wechung Maria Wang, Bin Chen, Yong Wan Jin, Jong Min Kim, Takenori Fujiwara, Sondra L. Hellstrom, Hang Woo Lee, Wei You, Joon Hak Oh, Shuhong Liu, Zhenan Bao |
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| Rok vydání: | 2009 |
| Předmět: |
Materials science
Macromolecular Substances Polymers Surface Properties Molecular Conformation Selective chemistry of single-walled nanotubes Carbon nanotube Chemical vapor deposition law.invention Biomaterials law Materials Testing Lyotropic Polymer chemistry Nanotechnology General Materials Science Colloids Particle Size chemistry.chemical_classification Aqueous solution General Chemistry Polymer Liquid Crystals Nanostructures Solutions Chemical engineering chemistry Lyotropic liquid crystal Surface modification Crystallization Biotechnology |
| Zdroj: | Small. 5:1019-1024 |
| ISSN: | 1613-6829 1613-6810 |
| DOI: | 10.1002/smll.200800640 |
| Popis: | The 1D structure of single-walled carbon nanotubes (SWNTs) leads to unique physical properties, which have been investigated extensively. Numerous applications and device prototypes have been demonstrated; however, most have used SWNTs grown in situ by chemical vapor deposition. This limits throughput and choice of substrate owing to the high growth temperatures involved. Solution-based postsynthesis device fabrication, typically involving purification, solubilization, chemical functionalization, cutting, and/ or controlled assembly of SWNTs, is more desirable because of low cost, scalability to large areas, and compatibility with flexible plastic substrates. Unfortunately, SWNTs are not readily soluble, and chemical functionalization strategies for their solubilization usually alter their electronic properties. Furthermore, to take full advantage of the anisotropic charge-transport properties of SWNTs and to enhance their performance in high-strength composite materials, it is necessary to align them over a large area. Noncovalent functionalization of SWNTs is a particularly attractive avenue for dispersion because it enables modification of material properties without altering the chemical structure of the nanotubes. To date, most high-concentration dispersions (>1mg mL ) have been obtained in aqueous solutions by mixing SWNTs with surfactants, doubleor |
| Databáze: | OpenAIRE |
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