(Z)-N′-(3-Ethyl-4-oxothiazolidin-2-ylidene)-2-[6-(4-methoxyphenyl)imidazo[2,1-b]thiazol-3-yl]acetohydrazide
| Autor: | Mehmet Akkurt, Cem Cüneyt Ersanlı, Zeliha Atioğlu, Rahmi Köseoğlu, Faika Başoğlu, Nuray Ulusoy Güzeldemirci |
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| Rok vydání: | 2017 |
| Předmět: |
crystal structure
imidazo[2 1-b][1 3]thiazole ring system Chemistry Hydrogen bond Stereochemistry imidazole ring Crystal structure Dihedral angle Triclinic crystal system hydrogen bonding 010402 general chemistry 010403 inorganic & nuclear chemistry Hydrazide Ring (chemistry) 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound thiazole ring thiazolidine ring lcsh:QD901-999 Imidazole lcsh:Crystallography Benzene |
| Zdroj: | IUCrData, Vol 2, Iss 1, p x170040 (2017) |
| ISSN: | 2414-3146 |
| DOI: | 10.1107/s2414314617000402 |
| Popis: | The title compound, C19H19N5O3S2, crystallizes in the triclinic space groupP-1, with two independent molecules (AandB) in the asymmetric unit (Z′ = 2). The imidazo[2,1-b][1,3]thiazole ring systems in moleculesAandBare essentially planar (r.m.s deviations = 0.004 and 0.005 Å, respectively), with dihedral angles of 1.1 (3) and 0.8 (3)°, respectively, between the thiazole and imidazole rings. The mean planes of these ring systems make dihedral angles of 16.0 (2) and 61.9 (2)° for moleculeA, and 11.8 (2) and 74.3 (2)° for moleculeB, with the 1,3-thiazolidine and methoxy-substituted benzene rings, respectively. In the crystal, molecules are linkedviaN—H...O hydrogen bonds, forming –A–B–A–B– chains along [100]. The chains are linked by C—H...O hydrogen bonds, forming layers parallel to theabplane. |
| Databáze: | OpenAIRE |
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