Voltammetric characterization of [ReO]3+ containing complexes

Autor:	Eduardo Méndez, Carlos Kremer, Ana M. Castro Luna, María Fernanda Cerdá Bresciano
Jazyk:	angličtina
Rok vydání:	2007
Předmět:	complexes Perrhenate Ligand Stereochemistry Carboxylic group chemistry.chemical_element rhenium Rhenium Medicinal chemistry Decomposition Redox Electrochemical response chemistry.chemical_compound chemistry Ciencias Exactas solutions
Zdroj:	SEDICI (UNLP) Universidad Nacional de La Plata instacron:UNLP
Popis:	In the present work, the voltammetric profiles of Au-pc in 1 mM solutions of K[ReVOCl2(L)] (L = dianions of H2hida or H2eida; hida, n-(2,6-dimethylphenyl carbamoylmethyl)imino diacetic acid, and eida, 2,6-diethyl ida) complexes were evaluated. The obtained electrochemical response was the result of the contributions coming from the [ReO]3+ core (Epa at ca. 0.2 V vs. Ag/AgNO3) and the carboxylic group of the ligand. There where also observed redox contributions ascribed to the presence of perrhenate coming from the decomposition of the complex with the lost of ligands, in agreement with the low stability of the studied complexes. copyright The Electrochemical Society. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas Facultad de Ciencias Exactas
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a0b9cfd4b2e8e8296a382ad37afc5203 http://sedici.unlp.edu.ar/handle/10915/83370 Zobrazit plný text záznamu