Crystal structure of a novel Hg(II) complex, [Hg(tri-2-furylphosphine)2(tri-2-furylphosphinoxide)3] [ClO4]2

Autor:	Rossana Galassi, Alfredo Burini, Fiorella Bachechi, Bianca Rosa Pietroni
Rok vydání:	2005
Předmět:	Inorganic Chemistry Crystallography Trigonal bipyramidal molecular geometry Chemistry Hexagonal crystal system Stereochemistry Organic Chemistry Molecule Crystal structure Tri-2-furylphosphine Spectroscopy Analytical Chemistry
Zdroj:	Journal of Molecular Structure. 740:119-123
ISSN:	0022-2860
Popis:	The Hg(II) complex [Hg(TFP)2(OTFP)3][ClO4]2 with TFP=tri-2-furyl-phosphine and OTFP=tri-2-furylphosphinoxide has been prepared and characterised. It crystallises in the hexagonal P63/m space group with Z=2, a=13.308(3), c=21.092 (4) A, V=3235(1) A3. The structure of the complex cation consists of independent molecules with Hg pentacoordinated in exact trigonal bipyramidal geometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a03cb49a5210350553cc0a07ecd6fbdb https://doi.org/10.1016/j.molstruc.2005.01.030 Zobrazit plný text záznamu Full Text from ScienceDirect