Synthesis and electrochemical characterization of original 'TEMPO' functionalized multiwall carbon nanotube materials: Application to iron (II) detection
| Autor: | Karine Gorgy, Luisa-Roxana Popescu Mandoc, Kamal Elouarzaki, Cristina-Andreea Amarandei, Michael Holzinger, Serge Cosnier, Eleonora-Mihaela Ungureanu |
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| Přispěvatelé: | MOLTECH-Anjou, Université d'Angers (UA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Département de Chimie Moléculaire - Biosystèmes Electrochimiques et Analytiques (DCM - BEA), Département de Chimie Moléculaire (DCM), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Detection limit
Materials science Stacking Carbon nanotube Electrochemistry law.invention Catalysis Electrochemical gas sensor lcsh:Chemistry chemistry.chemical_compound chemistry Chemical engineering lcsh:Industrial electrochemistry lcsh:QD1-999 law Molecule Pyrene Organic chemistry [CHIM]Chemical Sciences ComputingMilieux_MISCELLANEOUS lcsh:TP250-261 |
| Zdroj: | Electrochemistry Communications, Vol 60, Iss, Pp 131-134 (2015) Electrochemistry Communications Electrochemistry Communications, Elsevier, 2015, 60, pp.131-134. ⟨10.1016/j.elecom.2015.08.024⟩ |
| ISSN: | 1388-2481 |
| DOI: | 10.1016/j.elecom.2015.08.024⟩ |
| Popis: | We report the synthesis and electrochemical behavior of an original catalyst bearing a 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) unit and a pyrene group. Anchoring of this bi-functional molecule by π -stacking onto multiwalled carbon nanotubes allows the study of the electrochemical properties of the compound in the immobilized state. These resulting functionalized TEMPO materials were used to detect iron(II) in solution with an experimental detection limit of 3.9 × 10−8 mol L−1 and a linear range between 7.8 × 10−8 and 1.4 × 10−6 mol L−1. Keywords: TEMPO, Multiwalled carbon nanotubes, Pyrene, Iron(II), Electrochemical sensor |
| Databáze: | OpenAIRE |
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