NMR determination of concentration-switchable inclusion complex of a β-cyclodextrin derivative carrying a benzene group linked to a C,C-glucopyranoside spacer
| Autor: | Takashi Yamanoi, Kaname Katsuraya, Yoshiki Oda |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Cyclodextrin 010405 organic chemistry Stereochemistry Intermolecular force Intramolecular inclusion General Chemistry 010402 general chemistry Condensed Matter Physics Ring (chemistry) 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Crystallography β-Cyclodextrin conjugated with a guest molecule chemistry Intramolecular force Intermolecular inclusion Molecule Moiety Concentration-switchable inclusion complex Benzene Derivative (chemistry) Food Science |
| Zdroj: | Journal of Inclusion Phenomena and Macrocyclic Chemistry. 89(1-2):189-197 |
| ISSN: | 1388-3127 |
| Popis: | This article describes the structure of the inclusion complex that a β-cyclodextrin derivative 1, which includes a benzene ring tethered to a cyclodextrin moiety via a C,C-glucopyranoside spacer, forms when its concentration is 9 mM. As we have recently reported, 1 forms an intramolecular inclusion complex at a concentration of 2 mM. By contrast, detailed NMR structural analysis revealed that at a 9 mM concentration, 1 formed a symmetrical pseudo-dimer based on intermolecular inclusion complexiation between two molecules of 1. Thus, the inclusion structures of 1 varied depending on concentration, which indicates that the structure of this β-cyclodextrin derivative could be “concentration-switchable.” This is a post-peer-review, pre-copyedit version of an article published in Journal of Inclusion Phenomena and Macrocyclic Chemistry. The final authenticated version is available online at: http://dx.doi.org/10.1007/s10847-017-0746-0 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink