Stabilization of Long-Lived Metastable State in Long Alkylated Spin-Crossover Cobalt(II) Compound

Autor:	Kazuya Kato, Hokuto Yoshizaki, Satoshi Kawata, Yuuki Yamamoto, Akira Fuyuhiro, Yoshihiro Kojima, Daisuke Urakami, Shinya Hayami, Katsuya Inoue
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Relaxation (NMR) chemistry.chemical_element Alkylation Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Spin crossover Metastability Diamagnetism Physical and Theoretical Chemistry Terpyridine Cobalt Alkyl
Zdroj:	Inorganic Chemistry. 49:1428-1432
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic9015417
Popis:	The A mixed crystal compound [Co(0.8)Fe(0.2)(C16-terpy)(2)](BF(4))(2) (2) (C16-terpy is 4'-hexadecyloxy-2,2':6',2''-terpyridine) with long alkyl chains was prepared by mixing [Co(C16-terpy)(2)](BF(4))(2) (1), which exhibits unique magnetic behavior, and the diamagnetic iron(II) compound [Fe(C16-terpy)(2)](BF(4))(2) (3). The long-lived metastable state in the frozen-in effect was observed for the first time in the spin-crossover cobalt(II) compound 2. Furthermore, relaxation from metastable to stable states was very slow because of a large structural transition resulting from the long alkyl chains.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9fd2e9817ce1083bf6e78db57fdc3ee7 https://doi.org/10.1021/ic9015417 Zobrazit plný text záznamu