Insights into the mechanism for gold catalysis: behaviour of gold(I) amide complexes in solution

Autor:	Mariusz Bobin, Stephen Mark Roe, Iain J. Day, Eddy M. E. Viseux
Rok vydání:	2013
Předmět:	Combinatorial chemistry Catalysis Inorganic Chemistry RC0254 chemistry.chemical_compound QD0071 chemistry Mechanism (philosophy) Amide Freezing-point depression Physical chemistry QD QD0146 Single crystal QD0241 QD0450
Zdroj:	Dalton transactions (Cambridge, England : 2003). 42(18)
ISSN:	1477-9234 1477-9226
Popis:	We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes 1-7. The dinuclear complexes 6b and 7 were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9fd19c63549e1ce20e254a22d48dbd32 https://pubmed.ncbi.nlm.nih.gov/23478402 Zobrazit plný text záznamu