Mixing iron oxide nanoparticles with different shape and size for tunable magneto-heating performance
| Autor: | Federico Spizzo, Jesus G. Ovejero, Lucia Del Bianco, M. Puerto Morales |
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| Přispěvatelé: | Ministerio de Ciencia, Innovación y Universidades (España), European Commission, Ovejero, Jesús G. [0000-0003-3774-6589], Morales, M. P. [0000-0002-7290-7029], Bianco, L. Del [0000-0002-3110-7287], Spizzo, Federico [0000-0002-9134-4487], Ovejero, Jesús G., Morales, M. P., Bianco, L. Del, Spizzo, Federico |
| Rok vydání: | 2021 |
| Předmět: |
magnetic nanoparticles
Materials science SQUID magnetometry Nanoparticle Socio-culturale 02 engineering and technology 010402 general chemistry 7. Clean energy 01 natural sciences chemistry.chemical_compound elongated nanoparticles PE3_10 Magnetic properties General Materials Science nanomedicine applications Relaxation (NMR) 021001 nanoscience & nanotechnology hyperthermia tuning of magnetic properties 0104 chemical sciences Magnetic field Magnetic anisotropy chemistry Chemical physics 8. Economic growth Nanomedicine Nanoparticles 0210 nano-technology Order of magnitude Iron oxide nanoparticles Superparamagnetism |
| Zdroj: | Digital.CSIC. Repositorio Institucional del CSIC instname Nanoscale |
| Popis: | [EN] Tuning the magnetic properties of nanoparticles is a strategic goal to use them in the most effective way to perform specific functions in the nanomedicine field. We report a systematic study carried out on a set of samples obtained by mixing together iron oxide nanoparticles with different shape: elongated with aspect ratio ~5.2 and mean volume of the order of 103 nm3 (excluding the silica coating) and spherical with mean volume one order of magnitude larger. These structural features of the nanoparticles together with their aggregation state determine the magnetic anisotropy and the magnetic relaxation processes. In particular, the spherical nanoparticles turn out to be more stable against superparamagnetic relaxation. Mixing the nanoparticles in different proportions allows to modulate the magnetic response of the samples. The two populations of nanoparticles magnetically influence each other through a mean field mechanism, which depends crucially on temperature and rules the hysteretic magnetic properties and their thermal evolution. This magnetic phenomenology has a direct impact on the ability of the mixed samples to generate heat under an alternating magnetic field, a key function in view of nanomedicine applications. Under proper testing conditions, the heating efficiency of the mixed samples is larger compared to that obtained as the sum of those of the parent nanoparticles. This occurs thanks to the mean field produced by the magnetically blocked spherical nanoparticles that stabilizes the thermally fluctuating moments of the elongated ones, which therefore contribute more effectively to the heat production. This journal is the Spanish Ministry of Economy and Competitiveness under grant MAT2017-88148-R (AEI/FEDER, UE), PIE-201960E062 project and from the EU project H2020-FETOPEN-RIA 829162, HOTZYMES. |
| Databáze: | OpenAIRE |
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