Precipitation of calcium compounds onto rock surfaces in water with cementitious material

Autor: Yoshitaka Nara, Akimasa Nakao, Kazutoshi Shibuya, Hiroto Uchida, Koki Kashiwaya, Yusaku Hamada
Rok vydání: 2018
Předmět:
Zdroj: Carbonates and Evaporites. 34:1003-1020
ISSN: 1878-5212
0891-2556
DOI: 10.1007/s13146-018-0471-9
Popis: In this study, the precipitation of minerals onto rock surfaces was investigated to consider whether sealing of pores and cracks in rock can be accelerated. Cylindrical specimens were prepared and then kept in purified water with powders of high-strength and ultra-low-permeability concrete (HSULPC), which will be used to confine transuranic wastes in Japan. Then, the rock specimens were weighed and the surfaces of rock specimens were inspected under a microscope. It was recognized that precipitation occurred on the surface of the rock specimens. It was also shown that precipitation did not occur on rock specimens kept in water without HSULPC. The weight of all specimens stored in HSULPC increased, and the observed weight change was larger for rocks with higher porosities. It is concluded that precipitation of minerals occurs on the rock surface when the rock is kept in water with HSULPC powders. From the results obtained in this study, it is suggested that the sealing of pores and cracks in rock can be accelerated by the precipitation of calcium compounds using HSULPC. It is concluded that HSULPC is useful for underground radioactive waste disposal.
Databáze: OpenAIRE