Surface-Modified Carbon Felts: Possible Supports for Combinatorial Chemistry

Autor:	Estelle Coulon, Jean-Dominique Bourzat, Jean Pinson, Jean-Pierre Pulicani, Alain Commercon
Rok vydání:	2002
Předmět:	chemistry.chemical_classification Diazonium Compounds Chemistry Aryl Organic Chemistry chemistry.chemical_element Electrochemistry Combinatorial chemistry Merrifield resin chemistry.chemical_compound Suzuki reaction Specific surface area Nucleophilic substitution Organic chemistry Carbon
Zdroj:	The Journal of Organic Chemistry. 67:8513-8518
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo025880+
Popis:	It is possible to prepare carbon-based analogues of the Merrifield resin by electrochemical reduction of diazonium salts or oxidation of aryl acetates on high specific surface area carbon felts. These modified felts can undergo further reactions: nucleophilic substitution, Suzuki reaction, and finally reductive electrochemical cleavage, taking advantage of the conductivity of the carbon felt. This provides a simple example of the possible use of electrochemistry in combinatorial synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f61112e78da80d91e79fec45262ae26 https://doi.org/10.1021/jo025880+ Zobrazit plný text záznamu