Stress‐induced Domain Wall Motion in a Ferroelastic Mn3+ Spin Crossover Complex

Autor: Grace G. Morgan, Kane Esien, Vivien Zapf, Shalinee Chikara, Solveig Felton, Laurence C. Gavin, Elzbieta Trzop, Xiaxin Ding, Helge Müller-Bunz, Vibe B. Jakobsen, Michael A. Carpenter, Emiel Dobbelaar, Eric Collet
Přispěvatelé: Institut de Physique de Rennes (IPR), Université de Rennes (UR)-Centre National de la Recherche Scientifique (CNRS), School of Chemistry and Chemical Biology (UCD), University College Dublin [Dublin] (UCD), Department of Earth Sciences [Cambridge, UK], University of Cambridge [UK] (CAM), DE SC0019330, U.S. Department of Energy, GOIPG/2016/73, Irish Research Council, 18-0338, Augustinus Fonden, 12/IP/1703, Science Foundation Ireland, 17-3813, Oticon Fonden, 18-JI-0573, Reinholdt W. Jorck og Hustrus Fond, A.P. Møller og Hustru Chastine Mc-Kinney Møllers Fond til almene Formaal, EP/I036079/1, Engineering and Physical Sciences Research Council, DMR-1157490, National Science Foundation of Sri Lanka, Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS), Apollo - University of Cambridge Repository
Jazyk: angličtina
Předmět:
Diffraction
Phase transition
structural phase transition
Materials science
Spin states
Chemistry(all)
02 engineering and technology
domain wall
sub-03
010402 general chemistry
Space (mathematics)
01 natural sciences
Catalysis
spin crossover
Spin crossover
Phase (matter)
[CHIM.CRIS]Chemical Sciences/Cristallography
[CHIM.COOR]Chemical Sciences/Coordination chemistry
manganese(III)
Engineering(all)
Research Articles
Resonant ultrasound spectroscopy
[PHYS]Physics [physics]
34 Chemical Sciences
Condensed matter physics
General Medicine
General Chemistry
ferroelastic materials
021001 nanoscience & nanotechnology
0104 chemical sciences
3402 Inorganic Chemistry
Coordination Chemistry
Domain wall (magnetism)
[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]
Condensed Matter::Strongly Correlated Electrons
0210 nano-technology
51 Physical Sciences
Research Article
Zdroj: Jakobsen, V B, Trzop, E, Gavin, L C, Dobbelaar, E, Chikara, S, Ding, X, Esien, K, Müller-Bunz, H, Felton, S, Zapf, V S, Collet, E, Carpenter, M A & Morgan, G G 2020, ' Stress-Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex ', Angewandte Chemie-International Edition . https://doi.org/10.1002/anie.202003041
Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2020, 59 (32), pp.13305-13312. ⟨10.1002/anie.202003041⟩
Angewandte Chemie (International Ed. in English)
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2020, 59 (32), pp.13305-13312. ⟨10.1002/anie.202003041⟩
Jakobsen, V B, Trzop, E, Gavin, L C, Dobbelaar, E, Chikara, S, Ding, X, Esien, K, Müller-Bunz, H, Felton, S, Zapf, V S, Collet, E, Carpenter, M A & Morgan, G G 2020, ' Stress-Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex ', Angewandte Chemie, vol. 132, no. 32, pp. 13405-13412 . https://doi.org/10.1002/ange.202003041
ISSN: 0044-8249
1433-7851
1521-3773
DOI: 10.1002/anie.202003041
Popis: Domain wall motion is detected for the first time during the transition to a ferroelastic and spin state ordered phase of a spin crossover complex. Single‐crystal X‐ray diffraction and resonant ultrasound spectroscopy (RUS) revealed two distinct symmetry‐breaking phase transitions in the mononuclear Mn3+ compound [Mn(3,5‐diBr‐sal2(323))]BPh4, 1. The first at 250 K, involves the space group change Cc→Pc and is thermodynamically continuous, while the second, Pc→P1 at 85 K, is discontinuous and related to spin crossover and spin state ordering. Stress‐induced domain wall mobility was interpreted on the basis of a steep increase in acoustic loss immediately below the the Pc‐P1 transition
Stresses and strains: Domain wall motion is detected for the first time in a spin crossover crystal. Mobility of ferroelastic domain walls was interpreted on the basis of a steep increase in acoustic loss below a first order transition. Spin state ordering and domain formation is associated with collapse of the Jahn–Teller distortion on switching from the spin quintet to spin triplet form of a mononuclear Mn3+ complex.
Databáze: OpenAIRE
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