Synthesis of hypergrafted poly[4-(N,N-diphenylamino)methylstyrene] through tandem anionic-radical polymerization of radical-inimer

Autor:	Bingyong Han, Minglu Huang, Wantai Yang, Jianmin Lu, Xianhong Zhang
Rok vydání:	2017
Předmět:	Materials science Self-condensing vinyl polymerization Polymers and Plastics General Chemical Engineering Radical polymerization Multiangle light scattering 02 engineering and technology 010402 general chemistry 01 natural sciences Article chemistry.chemical_compound Polymer chemistry Materials Chemistry Side chain N-diphenylamino)methylstyrene) Reversible addition−fragmentation chain-transfer polymerization chemistry.chemical_classification Backbone chain Articles General Chemistry Polymer 021001 nanoscience & nanotechnology lcsh:TP1080-1185 0104 chemical sciences Anionic addition polymerization lcsh:Polymers and polymer manufacture chemistry Polymerization hypergrafted polymer 0210 nano-technology poly(4-(N
Zdroj:	Designed Monomers and Polymers Designed Monomers and Polymers, Vol 20, Iss 1, Pp 476-484 (2017)
ISSN:	1568-5551
DOI:	10.1080/15685551.2017.1365577
Popis:	In this paper, we present a tandem anionic-radical approach for synthesizing hypergrafted polymers. We prepared 4-(N,N-diphenylamino)methylstyrene (DPAMS) as a new radical-based inimer. Linear PDPAMS was prepared through anionic polymerization. Hypergrafted PDPAMS was synthesized through the self-condensing vinyl polymerization of DPAMS with linear PDPAMS. The linear backbone of PDPAMS, which incorporated latent radical initiating sites, served as a ‘hyperlinker’ to link hyperbranched side chains. The molecular weights of hypergrafted polymers increased as the length of the linear backbone chain increased. The hypergrafted structure of the resulting polymer was confirmed using a conventional gel permeation chromatograph apparatus equipped with a multiangle light scattering detector, nuclear magnetic resonance, differential scanning calorimetry, and thermogravimetric analysis. This strategy can be applied to synthesize other complex architectures based on hyperbranched polymers by changing the structure of a polymer backbone through anionic polymerization.
Databáze:	OpenAIRE
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