Lithium and magnesium complexes by using pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and application as catalysts for the hydroboration of carbonyl compounds

Autor:	Yafei Li, Huifen Pan, Yanhua Lu, Yanshu Luo, Yan Dang, Yalan Wang, Shengwang Xia, Yahong Li, Yuanzhi Xia
Rok vydání:	2022
Předmět:	Inorganic Chemistry
Zdroj:	Dalton Transactions. 51:3616-3624
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d1dt03235f
Popis:	The push for environmentally benign and sustainable chemical processes has reinforced the demand to displace transition metals with cheap, nontoxic and naturally abundant metals. To fulfil this requirement, we endeavored to synthesize alkali- and alkaline earth-metal complexes and employ them as catalysts for organic transformations. Two lithium and one magnesium complexes, which are supported by pyridyl-pendanted unsymmetrical β-diketiminates, have been synthesized and characterized. They are formulated as [Li(L
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9ebcc055889c83113146a043e0534c08 https://doi.org/10.1039/d1dt03235f Zobrazit plný text záznamu