Technology for obtaining modified oil sorbents
Autor: | Y. S. Peregudov, R. Mejri, Elena M. Gorbunova |
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Rok vydání: | 2021 |
Předmět: |
Materials science
Sorbent Geography Planning and Development Oxide Fraction (chemistry) 02 engineering and technology 010501 environmental sciences Management Monitoring Policy and Law engineering.material 01 natural sciences Food processing and manufacture chemistry.chemical_compound medicine 0105 earth and related environmental sciences TP368-456 021001 nanoscience & nanotechnology Environmentally friendly Carboxymethyl cellulose chemistry Chemical engineering Transmission electron microscopy glauconite activation modification hydrophobic agent oil sorbent technology engineering Stearic acid 0210 nano-technology Glauconite medicine.drug |
Zdroj: | Vestnik Voronežskogo Gosudarstvennogo Universiteta Inženernyh Tehnologij, Vol 82, Iss 4, Pp 247-253 (2021) |
ISSN: | 2310-1202 2226-910X |
DOI: | 10.20914/2310-1202-2020-4-247-253 |
Popis: | Expediency of using natural glauconite material as a basis for the production of an environmentally friendly sorbent with hydrophobic and magnetic properties for liquidating oil and oil products spills mechanically and using a magnetic field has been substantiated and experimentally proved. Fractional, elemental and oxide compositions of the original mineral have been studied. The structure of glauconite fraction 0.045-0.1 mm has been investigated by transmission electron microscopy. It was found that the surface of the sample particles is heterogeneous with a large number of pores and cracks. Based on the experimental data, the optimal conditions for the production and use of powder and granular sorbents based on glauconite with specified properties were determined, at which a high degree of recovery (more than 90%) of oil with water and hard surfaces. The optimum temperature for obtaining a magnetic oil sorbent is 400 °C. The doses of stearic acid and iron (III) oxide were established at 5 wt. %, which provide hydrophobicity and magnetic properties to the synthesized sorbent. A high degree of oil (97%) and oil (98%) recovery when using a sorbent is achieved at a ratio of 1: 10 to sorbate. To eliminate oil and oil product spills, it is proposed to use granular ferromagnetic sorbents obtained by introducing carboxymethyl cellulose into the modified glauconite composition. oil and oil products granular sorbent increases in comparison with the original mineral by 1.2–2.2 times. Technological schemes for obtaining ferromagnetic hydrophobic and granular sorbents based on glauconite for collecting oil and oil products from water and solid surfaces have been developed. The synthesized sorbents are characterized by high efficiency, low cost, and environmental friendliness. |
Databáze: | OpenAIRE |
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