Redox induced S-S bond cleavage of 2,2'-dithiobisbenzothiazole - leading to a [2Ru-2S] core analogous to [2Fe-2S] cluster

Autor:	Goutam Kumar Lahiri, Suman Dhara, Sanjib Kumar Panda
Rok vydání:	2021
Předmět:	Inorganic Chemistry chemistry.chemical_compound Electron transfer Crystallography chemistry Reducing equivalent Cluster (physics) chemistry.chemical_element Charge (physics) Redox Bond cleavage Ruthenium
Zdroj:	Dalton transactions (Cambridge, England : 2003). 50(36)
ISSN:	1477-9234
Popis:	Facile reduction of 2,2′-dithiobisbenzothiazole by the mediation of metal-to-ligand charge transfer or by internal reducing equivalent is demonstrated. It leads to various binding modes of thiolates (κ1, κ2, μ) in a series of mononuclear and dinuclear ruthenium complexes. The dinuclear complex exhibited electron transfer processes similar to a [2Fe-2S] cluster.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9e8d5c2eb02eae43ef4f95489f4a19f4 https://pubmed.ncbi.nlm.nih.gov/34378605 Zobrazit plný text záznamu