The unprecedented catalytic activity of alkanolamine CO2 scrubbers in the cycloaddition of CO2 and oxiranes: a DFT endorsed study
| Autor: | Bo Mi Kim, Yong Son Won, Amal Cherian Kathalikkattil, Jose Tharun, Kuruppathparambil Roshith Roshan, Dae-Won Park |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Metals and Alloys
General Chemistry Catalysis Cycloaddition Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Yield (chemistry) Materials Chemistry Ceramics and Composites Carbon dioxide scrubber Organic chemistry Amine gas treating Alkanolamine Selectivity |
| Zdroj: | Chemical communications (Cambridge, England). 50(89) |
| ISSN: | 1364-548X |
| Popis: | A novel application of alkanolamines, widely employed as CO2 scrubbers in catalyzing the insertion of CO2 into epoxides generating cyclic carbonates in excellent yield and selectivity via the synergistic activity of hydroxyl and amine groups, is unravelled along with computational studies. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|