A new reaction of vicinal sulfonyliminocarboxylates with phosphites

Autor:	Petro P. Onys’ko, T. I. Chudakova, Yuliya V. Rassukana, Olena A. Suvalova, Anatolii D. Sinitsa
Rok vydání:	2003
Předmět:	chemistry.chemical_classification Sulfonyl Chemistry Organic Chemistry General Medicine Biochemistry Medicinal chemistry Phosphorane chemistry.chemical_compound Group (periodic table) Drug Discovery Organic chemistry Propionates Vicinal Alkyl
Zdroj:	Tetrahedron Letters. 44:1855-1857
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(03)00097-2
Popis:	The reaction of alkyl trifluoro(organylsulfonylimino)propionates with phosphites occurs with NC transfer of the RSO2 group and leads to sulfonyl-substituted trifluoroalanine derivatives. The novel rearrangement is interpreted as cheletropic 1,4-cycloaddition of the phosphite and subsequent 1,2-shift of the sulfonyl group in the intermediate cyclic phosphorane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9e3719bf85757c97140eb7baf66b15b7 https://doi.org/10.1016/s0040-4039(03)00097-2 Zobrazit plný text záznamu Full Text from ScienceDirect