Optically active molecule-based magnets: Enantioselective self-assembling, optical, and magnetic properties
Autor: | Muriel Brissard, Michel Verdaguer, Michel Gruselle, Bernard Malézieux, Román Andrés, Cyrille Train |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Chirality. 13:712-714 |
ISSN: | 1520-636X 0899-0042 |
DOI: | 10.1002/chir.10023 |
Popis: | In this short communication we describe the synthesis and the optical and magnetic properties of optically active three dimensional (3D) bimetallic [Cr-Mn] networks [[Delta Cr(III) Delta Mn(II)(ox)(3)][Delta Ru(II)(bpy)(3)]ClO(4)](n)1 - Delta, [[Lambda Cr(III)Lambda Mn(II)(ox)(3)][Lambda Ru(II) (bpy)(3)]ClO(4)](n) 1 - Lambda and [[Delta Cr(III)Delta Mn(II)(ox)(3)][Delta Ru(II)(bpy)(2)p p y]](n) 2 - Delta,[[Lambda Cr(III)Lambda Mn(II)(ox)(3)][Lambda Ru(II)(bpy)(2)ppy]](n) 2 - Lambda (ox = oxalate, bpy = bipyridine, ppy = phenyl-pyridine). |
Databáze: | OpenAIRE |
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