Reactions between a sodium amide Na[N(SiMe3)R1] (R1= SiMe3, SiMe2Ph or But) and a cyanoalkane RCN (R = Ad or But)

Autor:	Peter B. Hitchcock, Anthony G. Avent, Floria Antolini, Michael F. Lappert, Andrey V. Protchenko, Alexei V. Khvostov
Rok vydání:	2006
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Nitrile Sodium amide Sodium chemistry.chemical_element Organic chemistry Benzene Medicinal chemistry Adduct
Zdroj:	Dalton Trans.. :919-927
ISSN:	1477-9234 1477-9226
DOI:	10.1039/b506753g
Popis:	Reactions between sodium amides Na[N(SiMe3)R1] [R1 = SiMe3 (1), SiMe2Ph (2) or But (3)] and cyanoalkanes RCN (R = Ad or But) were investigated. In each case the nitrile adduct [Na{mu-N(SiMe3)2}(NCR)]2 [R = Ad (1a) or But (1b)], trans-[Na{mu-N(SiMe3)(SiMe2Ph)}(NCR)]2 [R = Ad (2a) or But (2b)], [(Na{mu-N(SiMe3)But})3(NCAd)3] (3a) or [(Na{mu-N(SiMe3)But})3(NCBut)n] [n = 3 (3b) or 2 (3c)] was isolated. The reaction of complexes 3a or 3b with benzene afforded the ketimido complex [Na{mu-N=C(Ad)(Ph)}]6.2C6H6 (4a) or [Na{mu-N=C(But)(Ph)}]6 (4b); the former was also prepared in more conventional fashion from NaPh and AdCN. The synthesis and structure of an analogue of complex 1a, [Li{mu-N(SiMe3)2}(NCAd)]2 (5a), is also presented. The compounds 1a, 1b, 2a, 2b, 3, 3b, 4a, 4b and 5a were characterised by X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9da86a7d946aa4e761071abdc1714350 https://doi.org/10.1039/b506753g Zobrazit plný text záznamu