Toggling the Z-type interaction off-on in nickel-boron dihydrogen and anionic hydride complexes

Autor:	Jacob R. Prat, Ryan C. Cammarota, Brendan J. Graziano, James T. Moore, Connie C. Lu
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:8798-8801
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc03219h
Popis:	The boron metalloligand indirectly distorts the Ni geometry to facilitate H2 binding and stabilizes a reactive anionic Ni hydride via a direct Ni–B interaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d8da2f05a4f47397e7fe0628bce4778 https://doi.org/10.1039/d2cc03219h Zobrazit plný text záznamu