Zeolite synthesis in hydrated silicate ionic liquids

Autor:	Christine E. A. Kirschhock, Leen Van Tendeloo, Eric Breynaert, Mohamed Haouas, Johan A. Martens, Francis Taulelle
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Hydrolysis Coacervate chemistry law Ionic liquid Inorganic chemistry Physical and Theoretical Chemistry Crystallization Alkali metal Zeolite Silicate law.invention
Zdroj:	Faraday Discussions. 179:437-449
ISSN:	1364-5498 1359-6640
DOI:	10.1039/c4fd00234b
Popis:	Hydrated alkali silicate ionic liquids (HSIL) were prepared by hydrolysis of tetraethoxysilane (TEOS) in alkali hydroxide–water mixtures, inducing coacervation and phase separation. The resulting optically clear, homogenous silicate ionic liquid offers exceptional potential for monitoring zeolite crystallisation. This enhanced synthesis route provides access to analysis of speciation, mechanistic details of zeolite formation, and brings organic-template-free zeolite synthesis by design within reach.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d7343dae2f9781d13f20e74f16684a4 https://doi.org/10.1039/c4fd00234b Zobrazit plný text záznamu