Development of a sensitive liquid-liquid extraction and ultra-performance liquid chromatography-tandem mass spectrometry method for the analysis of carbaryl residues in fresh vegetables sold in Riyadh
| Autor: | Nora Abdullah AlFaris, Saikh Mohammad Wabaidur, Ayman Abdel Ghafar, Jozaa Zaidan ALTamimi, Zeid A. ALOthman, Tahany Saleh Aldayel |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Detection limit
Reproducibility Residue (complex analysis) Multidisciplinary Chromatography UPLC Mass spectrometry Fresh vegetables 02 engineering and technology 010501 environmental sciences 021001 nanoscience & nanotechnology Carbaryl 01 natural sciences High-performance liquid chromatography chemistry.chemical_compound chemistry Liquid chromatography–mass spectrometry Liquid–liquid extraction 0210 nano-technology lcsh:Science (General) Determination 0105 earth and related environmental sciences lcsh:Q1-390 |
| Zdroj: | Journal of King Saud University: Science, Vol 32, Iss 4, Pp 2414-2418 (2020) |
| ISSN: | 1018-3647 |
| Popis: | An UPLC- mass spectrometry method has been proposed for the screening of carbaryl residues in fresh vegetables. Carbaryl treated samples of lettuce, cucumber and spinach were procured and analyzed for a time period of fifteen days to find out the amount of carbaryl residue. A simple and effective liquid–liquid sample extraction technique has been implemented for extraction of carbaryl. Multiple reactions monitoring analysis mode considering two daughter transitions was used for quantitation and confirmation analysis of carbaryl. The developed method has been authenticated by establishing various validation parameters including, linear ranges (0.001–5.0 µg/mL), percent recovery, reproducibility (precision), limits of detection (0.0003 µg/mL) and limits of quantification (0.0009 µg/mL). The recoveries were obtained in the range of 96.0 and 99.5% (RSD |
| Databáze: | OpenAIRE |
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