SmI2-H2O-mediated 5-exo/6-exo lactone radical cyclisation cascades
| Autor: | Michael R. Webb, Irem Yalavac, Sarah E. Lyons, David J. Procter |
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| Rok vydání: | 2014 |
| Předmět: |
Models
Molecular Stereochemistry Stereoisomerism Crystallography X-Ray Catalysis Bridged Bicyclo Compounds Lactones Materials Chemistry chemistry.chemical_classification Samarium Bicyclic molecule Metals and Alloys Water Oxidation reduction General Chemistry Iodides Surfaces Coatings and Films Electronic Optical and Magnetic Materials Alkadienes chemistry Cyclization Reagent Ceramics and Composites Indicators and Reagents Oxidation-Reduction Lactone |
| Zdroj: | Chemical communications (Cambridge, England). 50(85) |
| ISSN: | 1364-548X |
| Popis: | The SmI2–H2O reagent system mediates challenging 5-exo/6-exo lactone radical cascade cyclisations that deliver carbo[5.4.0]bicyclic motifs in a diastereoselective, one-pot process that establish two new carbocyclic rings and four stereocentres. |
| Databáze: | OpenAIRE |
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