The peripheral and non-peripheral 2H-benzotriazole substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical studies of zinc derivatives
Autor: | Gülsev Dilber, Mahmut Durmuş, Halit Kantekin, Asiye Nas, Hasan Altunparmak |
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Rok vydání: | 2018 |
Předmět: |
Benzotriazole
Singlet oxygen chemistry.chemical_element 02 engineering and technology Manganese Zinc Carbon-13 NMR 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry Phthalonitrile chemistry.chemical_compound chemistry Phthalocyanine Proton NMR 0210 nano-technology Instrumentation Spectroscopy |
Zdroj: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 217 |
ISSN: | 1873-3557 |
Popis: | In this study, the novel 3-(1H-benzo[d][1,2,3]triazol-1-yl)methoxy substituted novel phthalonitrile compounds (2 and 6) were synthesized. Their non-peripheral and peripheral zinc (II) (3 and 7), manganese (III) (4 and 8) and copper (II) (5 and 9) phthalocyanine complexes were synthesized for the first time. These novel compounds were characterized by elemental analysis and different spectroscopic techniques such as FT-IR, UV-Vis, 1H NMR, 13C NMR and MALDI-TOF mass. Also, photochemical and photophysical properties of non-peripheral and peripheral substituted zinc (II) phthalocyanines (3 and 7) were investigated for determination of photodynamic therapy applications of these phthalocyanines. |
Databáze: | OpenAIRE |
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