Syntheses, crystal structures, and antibacterial activities of manganese(III), nickel(II), and copper(II) complexes containing a tetradentate Schiff base
| Autor: | Debasis Bandyopadhyay, Guillaume Pilet, Mahendra Ghosh, Anupam Ghosh, Bibekananda Mahanti, Michel Fleck |
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| Přispěvatelé: | bankura christian college, Institut für Mineralogie und Kristallographie, Universität Wien, Laboratoire des Multimatériaux et Interfaces (LMI), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Stereochemistry
chemistry.chemical_element Tetradentate Schiff base Manganese Crystal structure [CHIM.THER]Chemical Sciences/Medicinal Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Nickel(II) chemistry.chemical_compound Polymer chemistry Materials Chemistry [CHIM]Chemical Sciences Physical and Theoretical Chemistry Metal chloride Manganese(III) Schiff base [CHIM.MATE]Chemical Sciences/Material chemistry Copper 0104 chemical sciences Nickel Copper(II) chemistry Methanol Antibacterial activity |
| Zdroj: | Journal of Coordination Chemistry Journal of Coordination Chemistry, Taylor & Francis, 2012, 65 (22), pp.3884-3894. ⟨10.1080/00958972.2012.727990⟩ |
| ISSN: | 0095-8972 |
| DOI: | 10.1080/00958972.2012.727990⟩ |
| Popis: | International audience; Three new mononuclear Schiff-base complexes, namely [Mn(L)Cl] (1), [Ni(L)] (2), and [Cu(L)] (3), where L = anion of [N,N′-bis(2-hydroxybenzophenylidene)]propane-1,2-diamine, have been synthesized by reacting equimolar amounts of the respective metal chloride and the tetradentate Schiff base, H2L, in methanol. The complexes have been characterized by microanalytical, spectroscopic, single-crystal X-ray diffraction, and other physicochemical studies. Structural studies reveal that 1 adopts a distorted square-pyramidal geometry whereas 2 and 3 are isotypic with distorted square-planar geometries. The antibacterial activities of 1–3 along with their Schiff base have been tested against some Gram(+) and Gram(−) bacteria. |
| Databáze: | OpenAIRE |
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