Effects of biotransport and hydro-meteorological conditions on transport of trace elements in the Scott River (Bellsund, Spitsbergen)
Autor: | Łukasz Franczak, Żaneta Polkowska, Waldemar Kociuba, Stanisław Chmiel, Sara Lehmann-Konera |
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Rok vydání: | 2020 |
Předmět: |
Environmental Impacts
010504 meteorology & atmospheric sciences Drainage basin Weathering 010501 environmental sciences Ecosystem Science Transboundary pollutants 01 natural sciences General Biochemistry Genetics and Molecular Biology Nutrient Arctic Dissolved organic carbon Precipitation Long-range atmospheric transport Meltwater Dissolution 0105 earth and related environmental sciences geography geography.geographical_feature_category Aquatic and Marine Chemistry General Neuroscience Surface water General Medicine Biogeochemistry Glaciated catchment Metals Environmental chemistry Medicine General Agricultural and Biological Sciences Environmental Contamination and Remediation |
Zdroj: | PeerJ PeerJ, Vol 9, p e11477 (2021) |
ISSN: | 2167-8359 |
Popis: | The shaping of surface water chemistry in the Svalbard Archipelago is strongly dependent on the geology of the catchment and the process of long-range transport of atmospheric pollutants (LRATP). It was found that the dissolved trace elements in the Scott River, which catchment is characterized by a decreasing degree of glaciation, were of the natural origin (i.a. weathering and dissolution of local geological substratum). The exception was Zn originated from LRATP. The paper describe the influence changes in hydro-meteorological conditions and the presence of a seabird colony on the variability in the transport of trace elements within the Scott River catchment. The work assesses long-time fluctuations in the concentration of twenty five trace elements (i.a. Al, Cr, Cu, Pb, Sr, and Zn) from eighty-four surface water samples and their relation to changes in water discharge (Q), precipitation (P), pH, and dissolved organic carbon (DOC) at two river sites (with one being under the influence of the biotransport factor). Based on the results of matrix correlation and cluster analysis it was found that the additional load of DOC from the nesting site of Larus Argentatus in the mouth section of the river drastically changed the hydro-geochemical cycle of Co, Ni, Zn, Ga, Sr, Rb, Ba and U (0.30 < r < 0.51). Furthermore, the results of cluster analysis confirmed that the bird colony’s nesting site was strongly responsible for the presence of U, Rb, Zn, Ni and marine-derived nutrients (e.g. Se and Li). The discharge of glacier meltwater and the alkaline character of water have a negative effect on the dissolution of Li and Mn (−0.31 < r < −0.51), but positively affect the level of Rb and U (r = 0.31 and 0.35, respectively) due to it being washing out a seabird nesting colony in the mouth section of the Scott River. It was observed that the event of rises in air temperature and rain, which results in increased water discharge, caused an intense transport of the trace elements load. Moreover, results of the precipitation sensitivity coefficient factor (CF) proved that precipitation effect the occurrence of Li, Sr and U in the Scott River. |
Databáze: | OpenAIRE |
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