Spectral characterisation of a traditional Mesoamerican dye: relationship between in situ identification on the 16th century Codex Borbonicus manuscript and composition of Justicia spicigera plant extract
| Autor: | Anne Michelin, Ludovic Bellot-Gurlet, Lucie Arberet, Fabien Pottier, Christine Andraud, Witold Nowik |
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| Přispěvatelé: | Centre de Recherche sur la Conservation (CRC ), Muséum national d'Histoire naturelle (MNHN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de recherche des monuments historiques (LRMH), Muséum national d'Histoire naturelle (MNHN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS)-Muséum national d'Histoire naturelle (MNHN)-Ministère de la Culture et de la Communication (MCC)-Centre National de la Recherche Scientifique (CNRS), De la Molécule aux Nanos-objets : Réactivité, Interactions et Spectroscopies (MONARIS), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Fondation des Sciences du Patrimoine, Assemblée Nationale |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
In situ
Dye 02 engineering and technology HPLC-DAD 01 natural sciences Biochemistry Analytical Chemistry [CHIM.ANAL]Chemical Sciences/Analytical chemistry Botany Electrochemistry UV-Vis emission fluorescence Environmental Chemistry Spectroscopy biology Chemistry 010401 analytical chemistry [SHS.ART]Humanities and Social Sciences/Art and art history 021001 nanoscience & nanotechnology biology.organism_classification Mesoamerican dye Justicia spicigera 0104 chemical sciences Codex Borbonicus Colourant Pigment Raman spectroscopy Plant species Identification (biology) Composition (visual arts) 0210 nano-technology |
| Zdroj: | Analyst Analyst, Royal Society of Chemistry, 2021, 146 (8), pp.2520-2530. ⟨10.1039/D1AN00113B⟩ |
| ISSN: | 0003-2654 1364-5528 |
| Popis: | International audience; Characterisation of vegetal colourants in manuscripts is still a challenging task. Their identification using non-invasive techniques - since sampling is rarely possible - is valid only if there is evidence that the recorded signals are generated by compounds specific to the plant species. Otherwise, more extensive chemical characterisations are required to relate the non-invasive technique signals to the chemical composition of the dye extract and thus avoid misidentification. The case study of a traditional Mesoamerican dye found in the Codex Borbonicus is reported herein. The non-invasive identification of the colourant plant source and chemical characterisation of the coloured molecules were carried out through a multi-analytical technique approach. In situ Raman and UV-Vis emission fluorescence signals suggested the use of Justicia spicigera leaves to produce the brown paint layers of the manuscript. Analysis of the plant extract by liquid chromatography revealed that two compounds are mostly responsible for the colour, and these compounds were successfully isolated. Both contribute to the Raman spectra while only one of them is mainly responsible for the fluorescence recorded on Codex Borbonicus. |
| Databáze: | OpenAIRE |
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