High-Pressure ESR Spectroscopy: On the Rotational Motion of Spin Probes in Pressurized Ionic Liquids

Autor:	Boryana Y. Mladenova Kattnig, Daniel R. Kattnig, Guenter Grampp
Rok vydání:	2022
Předmět:	Rotation Viscosity Electron Spin Resonance Spectroscopy Materials Chemistry Ionic Liquids Physical and Theoretical Chemistry Surfaces Coatings and Films
Zdroj:	The Journal of Physical Chemistry B. 126:906-911
ISSN:	1520-5207 1520-6106
DOI:	10.1021/acs.jpcb.1c09243
Popis:	We report high-pressure (up to 50 MPa) ESR-spectroscopic investigations on the rotational correlation times of the nitroxide radicals 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO), 4-hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPOL), and 4-amino-2,2,6,6-tetramethylpiperidine 1-oxyl (ATEMPO) in the ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate (emimBF
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9c2b420c0560cfc535c57553272fc932 https://doi.org/10.1021/acs.jpcb.1c09243 Zobrazit plný text záznamu