Construction of SCO-Active Fe(II) Mononuclear Complexes from the Thio-pybox Ligand

Autor: Tao Liu, Yin-Shan Meng, Yuan-Yuan Zhu, Wan-Qing Gao, Chun-Hua Liu, Yao Pan, Qiang Liu
Rok vydání: 2020
Předmět:
Zdroj: Inorganic Chemistry. 59:7398-7407
ISSN: 1520-510X
0020-1669
DOI: 10.1021/acs.inorgchem.9b03506
Popis: The development of new spin-crossover complexes provides novel promising switching materials with significant potential at the molecular level. Ter-imine-type molecules represent one of the important classes of ligands in creating SCO-active complexes. Herein we report a family of mononuclear Fe(II) SCO-active compounds constructed from a new type of ter-imine ligand named the thio-pybox ligand (2,6-bis(4,4-dimethyl-4,5-dihydrothiazol-2-yl)pyridine
Databáze: OpenAIRE