Monoradical-containing four-coordinate Co(iii) complexes: homolytic S-S and Se-Se bond cleavage and catalytic isocyanate to urea conversion under sunlight
| Autor: | Chandan Mukherjee, Ganesh Chandra Paul, Samir Ghorai |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Metals and Alloys General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Isocyanate Medicinal chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Homolysis chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Urea Urea derivatives Bond cleavage |
| Zdroj: | Chemical communications (Cambridge, England). 53(57) |
| ISSN: | 1364-548X |
| Popis: | Four-coordinate, monoradical-containing Co(iii) complexes participated in the non-innocent ligand driven homolytic cleavage of S-S and Se-Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480) in dry CH2Cl2 under sunlight stimulus. |
| Databáze: | OpenAIRE |
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