Enhanced interfacial properties of novel amino acid-derived surfactants: Effects of headgroup chemistry and of alkyl chain length and unsaturation
| Autor: | José Enrique-Borges, Eduardo F. Marques, Rodrigo O. Brito, Sandra G. Silva, Marı́a Luisa C. Vale, Ricardo M.F. Fernandes |
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| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_classification
Chemistry Thermodynamics of micellization technology industry and agriculture Surfaces and Interfaces General Medicine Micelle Surface tension Surface-Active Agents Colloid and Surface Chemistry Pulmonary surfactant Critical micelle concentration Amphiphile Polymer chemistry Organic chemistry Surface Tension Physical and Theoretical Chemistry Counterion Amino Acids Alkyl Micelles Biotechnology |
| Zdroj: | Colloids and surfaces. B, Biointerfaces. 86(1) |
| ISSN: | 1873-4367 |
| Popis: | Amino acid-derived surfactants have increasingly become a viable biofriendly alternative to petrochemically based amphiphiles as speciality surfactants. Herein, the Krafft temperatures and critical micelle concentrations (cmc) of three series of novel amino acid-derived surfactants have been determined by differential scanning microcalorimetry and surface tension measurements, respectively. The compounds comprise cationic molecules based on serine and tyrosine headgroups and anionic ones based on 4-hydroxyproline headgroups, with varying chain lengths. A linear dependence of the logarithm of cmc on chain length is found for all series, and in comparison to conventional ionic surfactants of equal chain length, the new amphiphiles present lower cmc and lower surface tension at the cmc. These observations highlight their enhanced interfacial performance. For the 18-carbon serine-derived surfactant the effects of counterion change and of the presence of a cis-double bond in the alkyl chain have also been investigated. The overall results are discussed in terms of headgroup and alkyl chain effects on micellization, in the light of available data for conventional surfactants and other types of amino acid-based amphiphiles reported in the literature. |
| Databáze: | OpenAIRE |
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